沸石咪唑盐骨架
吸附剂
纳米复合材料
吸附
咪唑酯
萃取(化学)
氢氧化物
化学工程
解吸
色谱法
层状双氢氧化物
化学
材料科学
核化学
固相萃取
检出限
无机化学
金属有机骨架
有机化学
纳米技术
工程类
作者
Xin Di,Hanyang Wang,Xiaoli Guo,Xin Wang,Youping Li
标识
DOI:10.1016/j.jhazmat.2021.126753
摘要
For the first time, a novel nanocomposite, zeolitic imidazolate framework/magnetic layered double hydroxide (Fe3O4@LDH/ZIF), was successfully fabricated through in situ synthetic method with Fe3O4 as magnetic core and composite as shell. The resulting materials were characterized by XRD, TEM, FT-IR, VSM, TGA and nitrogen adsorption-desorption analysis. The Fe3O4@LDH/ZIF was employed as a sorbent in dispersive micro-solid phase extraction (D-μ-SPE) for enrichment of four endocrine disrupting compounds (EDCs) from milk samples prior to ultra-high performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS) analysis. The synthesized nanocomposite showed bigger specific surface area and better absorption capacity than Fe3O4@LDH. The equilibrium adsorption capacities (Qe, mg/g) of EDCs on the Fe3O4@LDH/ZIF reached up to 47.4-138.8 mg/g, mainly resulting from hydrogen bonding, π-π interaction and electrostatic interaction between EDCs and nanocomposite. Several variables affecting the extraction efficiency were investigated and optimized. The method displays low limits of detection (3-15 ng L-1), good linearity (10-5000 ng L-1), acceptable precision (RSD < 7.8%) and accuracy (RE < 5.2%). Satisfactory repeatability was obtained with RSD in the range of 1.2-7.8%. This work provides a promising approach for the development of new sorbent media in sample preparation for the improvement of analytical performance.
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