皮克林乳液
材料科学
石墨烯
氧化物
乳状液
聚脲
化学工程
光热治疗
相变材料
热能储存
热处理
相变
纳米颗粒
复合材料
纳米技术
涂层
冶金
工程类
生物
工程物理
生态学
作者
Onesmus Musyoki Maithya,Xiang Li,Xueling Feng,Xiaofeng Sui,Bijia Wang
标识
DOI:10.1007/s10853-020-04499-5
摘要
In this study, Pickering suspension polymerization was used to synthesize thermally stable microencapsulated phase change materials (microPCMs) with n-eicosane as the PCM, polyurea (PUA) as the shell, and graphene oxide (GO) as the colloidal stabilizer. Accordingly, the GO-modified microPCMs (GO@PUAmPCM) prepared at different GO emulsion concentrations were investigated and compared. These microcapsules exhibited high thermal storage of about 70% (180 J/g), leakage prevention, and high solar harvesting capacity with efficient photothermal conversion efficiency (60%). GO@PUAmPCM also showed good thermal reliability, and no leakage was observed after 100 heating and cooling cycles. The process developed herein can be embraced to fabricate highly efficient and reliable PCM microcapsules for solar energy harvesting.
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