光催化
材料科学
纳米复合材料
X射线光电子能谱
可见光谱
高分辨率透射电子显微镜
化学工程
磷化物
纳米颗粒
催化作用
制氢
核化学
光化学
镍
纳米技术
化学
有机化学
透射电子显微镜
工程类
光电子学
冶金
作者
Yangqing He,Fangling Zhang,Bei Ma,Na Xu,Lucas Binnah,Binghua Yao,Qian Yang,Dongjie Liu,Zhen Ma
标识
DOI:10.1016/j.apsusc.2020.146187
摘要
In this study, a highly efficient ternary 6.7%Au/Ni2P/g-C3N4 nanocomposite is rationally fabricated through a two-step hydrothermal followed by green photoreduction strategy. The XPS analysis, SEM and HRTEM images reveal that Ni2P and good nanoparticles (AuNPs) are successfully loaded onto the surface of g-C3N4 and heterojunction formed among them. The optimized 6.7%Au/0.5%Ni2P/g-C3N4 demonstrates the highest photocatalytic efficiency towards decomposition of levofloxacin hydrochloride with 88.23% removal rate and hydrogen generation rate of 78.65 μmol·g−1·h−1, in comparison with the binary 0.5%Ni2P/g-C3N4 (76.86%, 47.06 μmol·g−1·h−1) and pristine g-C3N4 (61.26%, 45.61 μmol·g−1·h−1). Notably, this is the first time using Ni2P and AuNPs co-modified g-C3N4-based nanocomposites to evaluate the photocatalytic degradation performance of levofloxacin hydrochloride. The study of the corresponding enhanced mechanism indicates that the dramatically improved photocatalytic performance is originated from the synergistic effects: including (1) the strong optical absorption property of Ni2P and the SPR effect of AuNPs endows the remarkably improved visible-light harvesting for increasing charge carrier production; (2) the co-catalysts of Ni2P and AuNPs play key roles as interfacial electron sinkers and facilitate photogenerated electron-hole pairs separation and migration; (3) the co-integration improves the specific surface area of final product which can provide more active sites for the improvement of photocatalytic performance. Moreover, a plausible degradation pathway for levofloxacin hydrochloride is proposed based on the UPLC-MS analysis. Our work highlights a good example for designing and constructing other highly-efficient g-C3N4-based multicomponent photocatalysts for both solar energy conversion and environmental remediation.
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