化学
硝化作用
元素分析
产量(工程)
表征(材料科学)
差示扫描量热法
起爆
组合化学
核磁共振波谱
有机化学
爆炸物
纳米技术
材料科学
热力学
物理
冶金
作者
Jinchao Ma,Jiaheng Zhang,Gregory H. Imler,Damon A. Parrish,Jean’ne M. Shreeve
出处
期刊:Organic Letters
[American Chemical Society]
日期:2020-06-09
卷期号:22 (12): 4771-4775
被引量:9
标识
DOI:10.1021/acs.orglett.0c01569
摘要
A new, safer, and more cost-effective methodology to synthesize salts based on gem-dinitromethyl-functionalized 5-amino-1,3,4-oxadiazolate is given. Cyclization, deprotection, nitration, and neutralization reactions were conducted to obtain products in high yield. All compounds were fully characterized by NMR and IR spectroscopy, elemental analysis, and differential scanning calorimetry. Crystal structure analysis, property tests, and theoretical calculations confirm good detonation performance and high mechanical stabilities of the salts.
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