结晶度
小角X射线散射
差示扫描量热法
材料科学
碳酸丙烯酯
高分子化学
热稳定性
锂(药物)
化学工程
共聚物
傅里叶变换红外光谱
聚合物
电解质
化学
物理化学
复合材料
散射
热力学
光学
物理
工程类
医学
内分泌学
电极
作者
Sabina Abbrent,Josef Pleštil,D. Hlavatá,Jan Lindgren,Jörgen Tegenfeldt,Å. Wendsjö
出处
期刊:Polymer
[Elsevier]
日期:2001-02-01
卷期号:42 (4): 1407-1416
被引量:275
标识
DOI:10.1016/s0032-3861(00)00517-6
摘要
The structural behaviour of a random copolymer consisting of polyvinylidene fluoride (PVdF) and hexafluoropropylene (HFP), when mixed with organic solvents and a lithium salt, has been investigated. In its neat form, the copolymer exhibits a semicrystalline matrix, where the PVdF constituent crystallises partially. The crystalline phase appears mostly as the non-polar (trans–gauche–trans–gauche′) phase II. The relative crystallinity of the PVdF domains remains constant on addition of a plasticiser, propylene carbonate (PC) or triethylene glycol dimethyl ether (TG), but is greatly decreased on addition of the salts lithium bis(trifluoromethane sulfone) imide, Li(TFSI) or lithium tetrafluoroborate, LiBF4. This is shown by the results from both wide-angle (WAXS) and small-angle (SAXS) X-ray scattering and FTIR-spectroscopy. Surprisingly, the addition of such a polar medium as the salt, and to a lesser extent the plasticisers, also causes a change in the structure of the crystalline phase to a more polar phase III (intermediate polar conformation). The thermal stability of the gels and the large influence the salt addition has on the material is also shown by the results from differential scanning calorimetry (DSC) measurements.
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