Photothermal techniques have been employed to measure optical and thermal properties of samples. This paper briefly introduces photothermal techniques and their applications in optical thin film coating measurements and Ti:sapphire laser crystal characterisation. Photothermal techniques can provide the information that pure optical spectroscopy is not able to give, such as optical-to-thermal energy conversion efficiency. Photothermal techniques have been proved as useful tools for quality test and improvement in modern optical manufacturing.