化学
海水
废水
四苯硼酸钠
工业废水处理
检出限
Mercury(编程语言)
色谱法
环境化学
甲苯
气相色谱法
环境工程
环境科学
有机化学
离子
地质学
程序设计语言
海洋学
计算机科学
作者
Kaori Shigeta,Hiroaki Tao,Katsuhiro Nakagawa,Tomoaki Kondo,Tetsuya Nakazato
出处
期刊:Analytical Sciences
[Japan Society for Analytical Chemistry]
日期:2018-02-01
卷期号:34 (2): 227-233
被引量:8
标识
DOI:10.2116/analsci.34.227
摘要
For determination of methylmercury (MeHg) and ethylmercury (EtHg) in seawater and industrial wastewater, a simple and robust analytical method was developed based on phenylation and solvent extraction followed by GC-MS measurement. Alkylmercury compounds were directly phenylated with sodium tetraphenylborate in water and extracted into toluene. The method detection limits obtained for MeHg and EtHg in pure water were 53.3 and 33.5 ng Hg L−1, respectively, which are almost 10 times lower than the environmental quality standards for water pollution in Japan (EQSJ): 0.5 μg Hg L−1. The recoveries of alkylmercury compounds from seawater and four kinds of industrial wastewater except for EtHg from treated wastewater of an optic lens factory were satisfactory (>90%) at 1- or 4-fold concentrations of the EQSJ. Contrarily, the low recovery of EtHg from the treated wastewater (75.4 ± 4.7%) was found to be caused by the rapid decomposition of EtHg into inorganic mercury.
科研通智能强力驱动
Strongly Powered by AbleSci AI