A high-entropy coordination cage featuring an Au-porphyrin metalloligand for the photodynamic therapy of liver cancer

We report a Pd-based hexagonal prismatic coordination cage of Pd-TMPP(Au) featuring a highly entropic ligand combination, viz. H2TMPP, TMPP(Pd), and TMPP(Au) metalloligands to yield double-arrow-shaped polycrystals. Pd-TMPP(Au) exhibits concentration-dependent cytotoxicity...