丝素
适应性
材料科学
自愈
丝绸
复合材料
医学
生态学
替代医学
病理
生物
作者
Huijuan Zhai,Yue Chen,Zhangpeng Li,Limin Ma,Tingting Wang,Hong Zhang,Jinqing Wang,Xianzhang Wu
标识
DOI:10.1002/asia.202400055
摘要
In order to solve typical problems of instability in a variety of environments, lack of self-healing ability and poor mechanical properties of traditional hydrogel materials, herein, a superelastic self-healing eutectogel of DPMS was designed and prepared in a deep eutectic solvent (DES) system using poly(vinyl alcohol) (PVA) as the bulk skeleton material, while two-dimensional MXene (Ti3C2TX) nanosheets and silk fibroin (SF) as reinforcing fillers. As a result, the prepared DPMS eutectogel possesses a high tensile strength of 7.63 MPa, while its elongation at break can reach 1115.2%, higher than most reported polymer hydrogels (<1000%). Moreover, this eutectogel shows excellent self-healing ability and can achieve rapid self-healing within 10 min, and its tensile strength and elongation at break can restore to 84.7% and 97.4% of the initial levels. More importantly, the eutectogel can withstand various environmental conditions, such as atmospheric or even vacuum evaporation and low-temperature freezing, while maintaining good mechanical and sensing performances. In addition, the eutectogel-assembled sensor has a high ionic conductivity of 0.61 S/m and a high strain sensitivity of 5.17 kPa-1. Besides, a stable electrical signal can be transmitted after 200 cycles at 30% strain.
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