氨
氨生产
硝酸盐
合理设计
还原(数学)
生化工程
工艺工程
纳米技术
环境科学
材料科学
化学
工程类
有机化学
几何学
数学
作者
Faiza Shafiq,Lei Yang,Weihua Zhu
摘要
into the environment. One method that is seen to be promising and could eventually replace the Haber-Bosch process is the electrocatalytic production of ammonia. However, in ambient conditions, the cleavage of the nitrogen molecule is exceedingly difficult. As a result, the yield of ammonia remains modest and the study's scope is still restricted to the lab. When the catalytic performance is significantly increased, nitrate and nitrite contaminations in water systems can be effectively removed and simultaneously transformed into energy sources if nitrites or nitrates are employed as nitrogen sources instead of nitrogen gas. This may become a new substitute for the synthesis of ammonia, but nitrate and nitrite reduction are not getting enough attention. In this review, we discuss the performance of the electrocatalytic nitrate reduction reaction, which includes cycling stability, reactivity, selectivity, and faradaic efficiency. Following this summary, we look into the crucial elements, the rate-determining step, and the reaction mechanisms that govern the performance of the nitrate reduction reaction. In order to support the practical use of the electrocatalytic nitrate reduction reaction, we finally provided a summary of the challenges and future directions guiding the design of efficient catalyst and reaction systems.
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