单斜晶系
化学
席夫碱
配体(生物化学)
镝
发光
结晶学
镧系元素
晶体结构
金属
分子
离子
无机化学
材料科学
光电子学
生物化学
受体
有机化学
作者
Yao-Yao Duan,Dong-Fang Wu,Huanhuan Chen,Yun-Juan Wang,Ling Li,Hong‐Ling Gao,Jian-Zhong Cui
出处
期刊:Polyhedron
[Elsevier]
日期:2022-10-01
卷期号:225: 116070-116070
被引量:8
标识
DOI:10.1016/j.poly.2022.116070
摘要
Six new rare earth metal complexes with the general formula [RE2(HL)2(dbm)2(CH3OH)2].2CH3OH (RE = Y (1), Tb (2), Dy (3), Ho (4), Er (5), Yb (6)) have been synthesized and constructed by Schiff base ligand and β-diketonate co-ligand. The single crystal X-ray structure study shows that 1–6 are phenoxo-O-bridged centrosymmetric dinuclear complexes and crystallize in the monoclinic P21/n space group. The near-infrared luminescent study indicates that complex 5 and 6 exhibit the characteristic emission peaks of the Er (III) and Yb (III) ions. Significantly, the emission peak of complex 5 at 1530 nm is located in the third telecommunication window of telecommunication, suggesting complex 5 has great potential application in modern telecommunication network. The alternating-current magnetic analysis reveals that the dysprosium complex exhibits single-molecule-magnet behavior under an applied dc field of 3000 Oe. In addition, the effective energy barrier of 3 is 12.45 K and pre-exponential factor is 1.08 × 10−6 s.
科研通智能强力驱动
Strongly Powered by AbleSci AI