化学
串联
烷基
光催化
烷基化
硼
相容性(地球化学)
光化学
功能群
有机化学
组合化学
催化作用
化学工程
聚合物
材料科学
工程类
复合材料
作者
Yu-Jie Li,Deguang Liu,Jin-Hu Ren,Tian-Jun Gong,Yao Fu
标识
DOI:10.1021/acs.joc.2c02923
摘要
Photocatalytic oxidation is a popular transformation way for organic synthesis and is widely applied in academia and industry. Herein, we report a blue light-induced alkylation-oxidation tandem reaction for the synthesis of diverse ketones by combining alkyl radical addition and oxidation of alkenyl borates. This reaction shows excellent functional group compatibility in acceptable yields, and diversity of radical precursors is applicable.
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