Modulating CsPbBr3 nanocrystals encapsulated in PCN-224(Zr) for boosting full-spectrum-driven CO2 reduction: S-scheme transfer, photothermal-synergistic effect, and DFT calculations

CsPbBr 3 @PCN-224(Zr) heterojunction exhibits enhanced full-spectrum-driven photocatalytic CO 2 RR activity promoted by S-scheme transfer and photothermal synergism with the highest CO yield and total electron consumption of 73.85 and 178.9 μmol g −1 h −1 .