硫黄
NAD+激酶
化学
催化作用
辅因子
金属
吸附
选择性
碳纤维
无机化学
人工光合作用
光催化
光化学
贵金属
烟酰胺
材料科学
酶
有机化学
复合数
复合材料
作者
Shusong Liu,Jiafu Shi,Jing Jia,Yuhan Yang,Shaohua Zhang,Dong Yang,Yu Chen,Shihao Li,Zhongyi Jiang
标识
DOI:10.1021/acscatal.3c03180
摘要
Light-driven regeneration of nicotinamide cofactors, primarily NADH, is of great significance for enzyme-photocoupled artificial photosynthesis, which strongly relies on the utilization of noble metal-based cocatalysts to ensure high selectivity of 1,4-NADH. Herein, we report a metal-free photocatalytic NADH regeneration system enabled by nitrogen and sulfur codoped carbon dots (N,S-CDs). The temporary occupation of the S element during catalyst synthesis increased the proportion of pyrrolic N by 2.05 times. The high proportion (88.44%) of pyrrolic N in N,S-CDs affords appropriate adsorption energy toward #4 carbon of the NAD+ pyridine ring. As a result, N,S-CDs exhibited a selectivity of 82.00 ± 5.64% toward 1,4-NADH, the highest value in the existing metal-free systems, which also showed a size-dependent 1,4-NADH regeneration yield with an optimal value of 42.92 ± 2.24%.
科研通智能强力驱动
Strongly Powered by AbleSci AI