硫酸
热重分析
热分解
烘烤
反应级数
差热分析
动力学
分解
材料科学
化学动力学
反应机理
热分析
频率因子
化学
反应速率
化学分解
活化能
无机化学
热的
化学分解过程
热力学
物理化学
冶金
反应速率常数
有机化学
催化作用
物理
量子力学
光学
衍射
作者
Xiuyan Wang,Jiemin Liu,Mei Li,Huili Fan,Qi-Shan Yang
出处
期刊:Rare Metals
[Springer Science+Business Media]
日期:2010-03-27
卷期号:29 (2): 121-125
被引量:27
标识
DOI:10.1007/s12598-010-0021-7
摘要
Baotou RE concentrate was decomposed with concentrated sulfuric acid by controlling the roasting temperature below 500°C. Thermogravimetry-differential thermal analysis (TG-DTA) and chemical analytical methods were used to study the thermal decomposition process and the thermal decomposition effect. The Freeman-Carroll method was applied to analyze the TG-DTA curves. The activation energy, reaction order, and reaction frequency factor at different stages were calculated. The Satava method was used to deduce the reaction mechanism and the relative reaction rate during the thermal decomposition process.
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