甲脒
钙钛矿(结构)
结晶度
碘化物
三碘化物
材料科学
冷凝
化学工程
钙钛矿太阳能电池
能量转换效率
晶界
无机化学
化学
结晶学
物理化学
复合材料
微观结构
光电子学
热力学
色素敏化染料
工程类
物理
电解质
电极
作者
Jianghu Liang,Anxin Sun,Zhanfei Zhang,Yiting Zheng,Xueyun Wu,Congcong Tian,Zhenhua Chen,Chun‐Chao Chen
出处
期刊:ACS materials letters
[American Chemical Society]
日期:2023-04-10
卷期号:5 (5): 1395-1400
标识
DOI:10.1021/acsmaterialslett.3c00115
摘要
The perovskite films prepared by the sequential deposition method suffer from incomplete lead iodide (PbI2) reaction, which is manifested by the poor photostability of the prepared perovskite solar cells. Herein, 2-thiophenemethylammonium (TMA), known for the formation of Ruddlesden–Popper layered perovskites, is used to modify the PbI2 film. The introduction of TMA reduces the crystallinity of PbI2 and participates in the formation of the solvent intermediate phase, thus promoting the formation of α-formamidinium lead triiodide (α-FAPbI3) perovskite films in the whole film thickness direction. Most of TMA escapes from the film by deprotonation, and only trace amounts of TMA (0.02%) and the condensation product (TMFA, 0.10%) between TMA and formamidinium (FA) are found to be strongly bonded to the perovskite grain boundaries. The results show that the stability of the perovskite solar cell is improved and the power conversion efficiency reaches 24.5%. This discovery confirms the great value of volatile alkylammoniums in the preparation and stabilization of α-FAPbI3 perovskite films.
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