催化作用
双功能
微波食品加热
热重分析
热解
双功能催化剂
材料科学
产量(工程)
碳纤维
化学工程
化学
有机化学
复合材料
复合数
工程类
物理
量子力学
作者
Juan Luo,Guojin Gong,Rui Ma,Shichang Sun,Chongwei Cui,Han Cui,Jiaman Sun,Ning Ma
出处
期刊:Fuel
[Elsevier]
日期:2023-08-01
卷期号:346: 128296-128296
被引量:5
标识
DOI:10.1016/j.fuel.2023.128296
摘要
A series of bifunctional catalysts (Fe-Ni/SiC) with microwave absorption and catalytic abilities were constructed to realize high-value application of waste plastics by microwave catalytic pyrolysis. The bifunctional performances and mechanisms were explored by a new microwave thermogravimetric oven. The bifunctional catalysts had good pore structure and the active components of Fe2O3, NiO, and NiFe2O4, which made the catalysts with good dielectric and catalytic performances. After catalysis, the heating rates and weight loss rates of low-density polyethylene were 68.18–73.39 °C·min−1 and 0.59–0.68 g·min−1, respectively. The increase in heating rate helped to promote the pyrolysis degree, advance the pyrolysis endpoint, and reduce the energy consumption (11.54 MJ/kg at most). When the catalyst was Fe-Ni/SiC (2:1), the highest gas yield (73.61 wt%) and H2 content (73.89 vol%) was obtained. Moreover, the higher graphitization degree of carbon nanotubes was obtained with more Fe loading. The oriented production of high-value products could be realized by adjusting the type and proportion of active components in the catalyst.
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