Spatially Confined Fe7S8 Nanoparticles Anchored on a Porous Nitrogen-Doped Carbon Nanosheet Skeleton for High-Rate and Durable Sodium Storage

材料科学 纳米片 多孔性 化学工程 氮气 纳米颗粒 兴奋剂 碳纤维 无机化学 纳米技术 复合材料 冶金 有机化学 复合数 工程类 化学 光电子学
作者
Tiantian Tang,Gaoya Ren,Yi Wen,Mixue Lu,Zhujun Yao,Tiancun Liu,Shenghui Shen,Haijiao Xie,Xinhui Xia,Yefeng Yang
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:15 (25): 30249-30261 被引量:19
标识
DOI:10.1021/acsami.3c04549
摘要

Iron sulfides are widely explored as anodes of sodium-ion batteries (SIBs) owing to high theoretical capacities and low cost, but their practical application is still impeded by poor rate capability and fast capacity decay. Herein, for the first time, we construct highly dispersed Fe7S8 nanoparticles anchored on a porous N-doped carbon nanosheet (CN) skeleton (denoted as Fe7S8/NC) with high conductivity and numerous active sites via facile ion adsorption and thermal evaporation combined procedures coupled with a gas sulfurization treatment. Nanoscale design coupled with a conductive carbon skeleton can simultaneously mitigate the above obstacles to obtain enhanced structural stability and faster electrode reaction kinetics. With the aid of density functional theory (DFT) calculations, the synergistic interaction between CNs and Fe7S8 can not only ensure enhanced Na+ adsorption ability but also promote the charge transfer kinetics of the Fe7S8/NC electrode. Accordingly, the designed Fe7S8/NC electrode exhibits remarkable electrochemical performance with superior high-rate capability (451.4 mAh g-1 at 6 A g-1) and excellent long-term cycling stability (508.5 mAh g-1 over 1000 cycles at 4 A g-1) due to effectively alleviated volumetric variation, accelerated charge transfer kinetics, and strengthened structural integrity. Our work provides a feasible and effective design strategy toward the low-cost and scalable production of high-performance metal sulfide anode materials for SIBs.
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