环氧树脂
材料科学
亚麻籽油
复合材料
环氧化大豆油
纤维
原材料
有机化学
化学
作者
Davide Sangaletti,Luca Ceseracciu,Lara Marini,Athanassia Athanassiou,Arkadiusz Żych
标识
DOI:10.1016/j.resconrec.2023.107205
摘要
In the last decades fiber-reinforced polymer composites (FRPC) have seen an enormous growth however, at the end of their lifetime, FRPC made of epoxy resins cannot be easily recycled because of the permanently crosslinked structure of the resins. Since the fibrous reinforcements usually have high costs, the possibility of developing recyclable FRPC is very advantageous both from environmental and economical point of view. To address this increasing need of the market, we developed a recyclable, environmentally friendly vitrimer resin from epoxidized linseed oil and a boronic ester cross-linker. Using the vitrimer as a matrix, carbon fiber-reinforced composites, with mechanical performance similar to the ones prepared with a conventional epoxy resin, were obtained. Moreover, the composites could be conveniently recycled under mild conditions by reversible hydrolysis of the boronic ester crosslinks using aqueous EtOH, recovering both the carbon fiber reinforcement and the vitrimer matrix.
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