High-Performance Silicone Sponge Evaporators with Low Thermal Conductivity for Long-Term Solar Interfacial Evaporation and Freshwater Harvesting

Solar interfacial evaporation (SIE) has emerged as a highly promising approach for sustainable freshwater harvesting. However, maintaining a stable evaporation rate and achieving a high freshwater yield in high-salinity brines remain a significant challenge. In this study, we present the development of silicone sponge-based evaporators with a “free-salt” structure, designed to enhance the efficiency of SIE and freshwater collection. These evaporators, designated as PSS@Fe3O4/CNTs, were fabricated by grafting durable silicone onto a silicone sponge framework, followed by the incorporation of Fe3O4 nanoparticles and carbon nanotubes. The unique combination of exceptional photothermal properties and a controlled yolk–shell structure with low thermal conductivity enabled the PSS@Fe3O4/CNT evaporators to sustain a stable evaporation rate of 1.87 kg m–2 h–1 in real seawater over 200 h of continuous operation under 1 sun illumination. Importantly, no salt accumulation was observed on the evaporator surfaces, even when exposed to highly concentrated brines. In a closed system equipped with a condenser, these evaporators achieved freshwater production rates of 14.5 and 11.8 kg m–2 over 10 h from 10 and 20 wt % NaCl solutions, respectively, under 1 sun illumination. These values correspond to normalized production rates of 1.45 and 1.18 kg m–2 h–1, showcasing the consistent and efficient performance of the evaporators across varying salinity levels. Beyond salt rejection, the PSS@Fe3O4/CNT evaporators also demonstrated the ability to effectively remove various heavy metal ions (e.g., Cu2+ and Zn2+) and organic pollutants from contaminated water. This work provides valuable insights into innovative evaporator designs for efficient freshwater production from seawater and wastewater.