材料科学
电解质
离子电导率
碳酸乙烯酯
化学工程
锂(药物)
聚合物
六氟丙烯
准固态
储能
共聚物
高分子化学
电极
复合材料
化学
四氟乙烯
色素敏化染料
功率(物理)
物理化学
内分泌学
工程类
物理
医学
量子力学
作者
Yufeng Liang,Tingting Feng,Jintian Wu,Jie Tan,Guotao Chen
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2023-04-28
卷期号:5 (5): 3564-3573
被引量:2
标识
DOI:10.1021/acsapm.3c00229
摘要
Solid-state lithium metal batteries (LMBs) are considered as one of the promising contenders for next-generation energy storage systems because of their high energy density and high safety performance. Since all-solid-state electrolytes are still hampered by low electrical conductivity and interfacial incompatibility, gel polymer electrolytes (GPEs) are more preferable with high ionic conductivities comparable to liquid electrolytes at room temperature and good contact with the electrodes. In this study, a high-performance composite GPE of semi-interpenetrating polymer networks, denoted as NVPH, was synthesized by in situ copolymerization of neopentyl glycol diacrylate (NPGDA) and vinyl ethylene carbonate monomers in an electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofiber matrix. NVPH shows a high ionic conductivity (2.89 × 10–3 S cm–1), a high voltage resistance (up to 5.2 V), enhanced mechanical strength (13.8 MPa), and a large lithium transfer number (0.57) at room temperature. Most importantly, it also exhibits high stability to lithium metal anodes and effectively prevents lithium dendrite growth for long cycle life in LFP|NVPH|Li batteries, which will facilitate the practical application of LMBs.
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