Emerging Materials and Strategies for Passive Daytime Radiative Cooling

Abstract In recent decades, the growing demands for energy saving and accompanying heat mitigation concerns, together with the vital goal for carbon neutrality, have drawn human attention to the zero‐energy‐consumption cooling technique. Recent breakthroughs in passive daytime radiative cooling (PDRC) might be a potent approach to combat the energy crisis and environmental challenges by directly dissipating ambient heat from the Earth to the cold outer space instead of only moving the heat across the Earth's surface. Despite significant progress in cooling mechanisms, materials design, and application exploration, PDRC faces potential functionalization, durability, and commercialization challenges. Herein, emerging materials and rational strategies for PDRC devices are reviewed. First, the fundamental physics and thermodynamic concepts of PDRC are examined, followed by a discussion on several categories of PDRC devices developed to date according to their implementation mechanism and material properties. Emerging strategies for performance enhancement and specific functions of PDRC are discussed in detail. Potential applications and possible directions for designing next‐generation high‐efficiency PDRC are also discussed. It is hoped that this review will contribute to exciting advances in PDRC and aid its potential applications in various fields.