催化作用
化学
臭氧
吸附
废水
工业废水处理
废物管理
化学工程
有机化学
工程类
作者
Wei Shi,Xiaojing Liu,Yulei Liu,Dong Li,Xili Tong,Jun Ma,Lu Wang
标识
DOI:10.1016/j.jhazmat.2023.130759
摘要
Development of robust, reactive, and inexpensive catalyst for pollutants abatement with catalytic ozonation is of great significance. Herein, the effect of a robust and easy-recovery catalyst, Fe2O3/Al2O3-SiC, for the catalytic ozonation of hardly biodegradable COD (hard COD) in coking wastewater had been explored. Al-O-Si bond formed on modified SiC through the substitution of hydrogen in surficial Si-OH groups by Al3+. The Lewis acid sites improved the adsorption of ozone and facilitated the formation of ·OH and O2·-. For coking wastewater treatment, the removal ratio of hard COD and the generation speed of hydroxyl radical (Rct) in the catalytic ozonation process were 71% and 253% higher than those in the ozonation group, respectively. Ozone utilization increased from 0.44 g COD removed/g O3 in the ozonation group to 1.42 g COD removed/g O3 in the Fe2O3/Al2O3-SiC catalytic ozonation group. In a full-scale application, Fe2O3/Al2O3-SiC catalytic ozonation decreased the consumption of O3 to 60 mg L-1 and decreased the operation cost by 50%. These results provided an approachable way for sharing the extraordinary capacity of ozone for contaminants remediation in industrial applications.
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