化学
单层
组合化学
金属
高分子化学
二硫键
有机化学
生物化学
作者
Lorenzo Delarue Bizzini,Patrick Zwick,Marcel Mayor
标识
DOI:10.1002/ejoc.201901283
摘要
A method for the transformation of organic thioacetates, a widely used functionality for the preparation of self‐assembled monolayers on gold surfaces, into unsymmetrical disulfides is reported. Disulfides are readily immobilized on gold in contrast to thioacetates, which usually require a deprotection step prior to bonding to the metal surface. The potential of the method for the controlled preparation of unsymmetrical disulfides has been demonstrated with model compounds comprising several thioacetates, which were readily converted into the corresponding unsymmetrical disulfides.
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