期刊:Acs Symposium Series [American Chemical Society] 日期:1993-05-05卷期号:: 427-437被引量:2
标识
DOI:10.1021/bk-1993-0523.ch033
摘要
The viability of one particular use of a membrane reactor for partial oxidation reactions has been studied through mathematical modeling. The partial oxidation of methane has been used as a model selective oxidation reaction, where the intermediate product is much more reactive than the reactant. Kinetic data for V 2 O 5 /SiO 2 catalysts for methane partial oxidation are available in the literature and have been used in the modeling. Values have been selected for the other key parameters which appear in the dimensionless form of the reactor design equations based upon the physical properties of commercially available membrane materials. This parametric study has identified which parameters are most important, and what the values of these parameters must be to realize a performance enhancement over a plug-flow reactor.