Fumed Silica — Rheological Additive for Adhesives, Resins, and Paints
作者
Herbert Barthel,Michael Dreyer,Torsten Gottschalk‐Gaudig,В. Ф. Литвинов,Е. А. Никитина
标识
DOI:10.1002/9783527620777.ch117d
摘要
Fumed silica, a synthetic silicon dioxide, is a powerful rheological additive for resins and paints to introduce thixotropy or even a yield point. The rheological effectiveness of fumed silica is based on its ability to form percolating networks which immobilize large volumes of liquid. By a combination of advanced rheological experiments, spectroscopic investigations, and quantum chemical calculations it could be demonstrated that the formation and stability of the silica network is strongly influenced by particle-resin interactions. The results can be used to develop comprehensive models, which explain the rheological performance of different grades of fumed silica in different resins.