超级电容器
材料科学
电容
循环伏安法
电化学
水溶液
电导率
制作
化学工程
纳米技术
功率密度
复合数
兴奋剂
纳米管
电极
碳纳米管
复合材料
光电子学
化学
物理化学
功率(物理)
病理
工程类
替代医学
物理
医学
量子力学
作者
Wenjie Zhong,Shangbin Sang,Yingying Liu,Qiong Wu,Kaiyu Liu,Hongtao Liu
标识
DOI:10.1016/j.jpowsour.2015.06.052
摘要
Highly ordered TiO2 nanotube arrays (NTAs) with excellent stability and large specific surface area make them competitive using as supercapacitor materials. Improving the conductivity of TiO2 is of great concern for the construction of high-performance supercapacitors. In this work, we developed a novel approach to improve the performance of TiO2 materials, involving the fabrication of Al-doped TiO2 NTAs by a simple electrochemical cathodic polarization treatment in AlCl3 aqueous solution. The prepared Al-doped TiO2 NTAs exhibited excellent electrochemical performances, attributing to the remarkably improved electrical conductivity (i.e., from approx. 10 kΩ to 20 Ω). Further analysis showed that Al3+ ions rather than H+ protons doped into TiO2 lattice cause this high conductivity. A MnO2/Al–TiO2 composite was evaluated by cyclic voltammetry, and achieved the specific capacitance of 544 F g−1, and the Ragone plot of the sample showed a high power density but less reduction of energy density. These results indicate that the MnO2/Al–TiO2 NTAs sample could be served as a promising electrode material for high -performance supercapacitors.
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