化学
荧光
Mercury(编程语言)
双功能
生物物理学
检出限
光化学
纳米技术
生物化学
色谱法
催化作用
光学
物理
材料科学
程序设计语言
生物
计算机科学
作者
Jianfei Liu,Jie Li,Jun Tang,Xiaopeng Yang,Di Zhang,Yong Ye,Yufen Zhao
出处
期刊:Talanta
[Elsevier]
日期:2021-11-01
卷期号:234: 122606-122606
被引量:32
标识
DOI:10.1016/j.talanta.2021.122606
摘要
Mercury and sulfur dioxide (SO2) are common pollutants in the ecological environment, which are important factors causing many diseases of organisms. The lack of appropriate analytical tools has limited the further understanding of the relationship between ionic mercury (Hg2+) and SO2. Herein, a bifunctional fluorescent probe LJ was designed and explored to simultaneously detect Hg2+ and SO2 via desulfurization reaction and Michael addition reaction, respectively. Probe LJ showed distinct fluorescence responses which a large near-infrared fluorescence enhancement towards Hg2+ at λem = 713 nm and a blue shift at λem = 450 nm towards SO2 without any spectral cross interferences. To the best of our knowledge, this is the first fluorescent probe with dual fluorescent emission channels to detect Hg2+ and SO2 with the detection limit of 187 nM and 354 nM, respectively. Moreover, cell fluorescent imaging experiments indicated that the probe was mitochondria targetable and provided evidence that SO2 could be used as an antidote to attenuate the toxicity of Hg2+ in living cells.
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