加氢脱氧
愈创木酚
催化作用
化学
木质素
热解
茴香醚
有机化学
苯酚
生物量(生态学)
甲酚
选择性
海洋学
地质学
作者
Shelaka Gupta,M. Ali Haider
出处
期刊:Elsevier eBooks
[Elsevier]
日期:2022-01-01
卷期号:: 409-430
标识
DOI:10.1016/b978-0-12-823306-1.00007-8
摘要
Bio-oil obtained from the pyrolysis of waste biomass is a potential alternative to fossil fuels. However, the presence of high oxygen content makes it unsuitable for direct use as a fuel, and therefore, upgradation of bio-oil is required. The catalytic hydrodeoxygenation (HDO) has been widely used for the upgradation of bio-oil to transportation fuels and value-added chemicals. However, since bio-oil is a complex mixture of different compounds, the exact mechanism for the bio-oil HDO is unknown. Phenolics, such as m-cresol, guaiacol, phenol, anisole, etc., derived from lignin pyrolysis, have been widely studied as model compounds to understand the HDO pathway of bio-oil. The activity and selectivity of these reactions are governed by different catalytic parameters, such as type of metal and support, nature of active sites, size of the catalyst, etc. The effect of these parameters on the selective production of aromatics and cyclic hydrocarbons through HDO of phenolics is briefly discussed in this chapter. In order to develop an efficient catalyst for the HDO reactions metal functionality, the optimum ratio of acid sites and acidity of the support should be taken into consideration.
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