Bifacial Si heterojunction-perovskite organic-inorganic tandem to produce highly efficient (ηT* ∼ 33%) solar cell

串联 钙钛矿(结构) 异质结 光电子学 材料科学 钙钛矿太阳能电池 薄膜 能量转换效率 太阳能电池 纳米技术 化学 结晶学 复合材料
作者
Reza Asadpour,Raghu Vamsi Krishna Chavali,M. Ryyan Khan,Muhammad A. Alam
出处
期刊:Applied Physics Letters [American Institute of Physics]
卷期号:106 (24) 被引量:94
标识
DOI:10.1063/1.4922375
摘要

As single junction thin-film technologies, both Si heterojunction (HIT) and Perovskite based solar cells promise high efficiencies at low cost. One expects that a tandem cell design with these cells connected in series will improve the efficiency further. Using a self-consistent numerical modeling of optical and transport characteristics, however, we find that a traditional series connected tandem design suffers from low Jsc due to band-gap mismatch and current matching constraints. It requires careful thickness optimization of Perovskite to achieve any noticeable efficiency gain. Specifically, a traditional tandem cell with state-of-the-art HIT (24%) and Perovskite (20%) sub-cells provides only a modest tandem efficiency of ~25%. Instead, we demonstrate that a bifacial HIT/Perovskite tandem design decouples the optoelectronic constraints and provides an innovative path for extraordinary efficiencies. In the bifacial configuration, the same state-of the-art sub-cells achieve a normalized output of 33%, exceeding the bifacial HIT performance at practical albedo reflections. Unlike the traditional design, this bifacial design is relatively insensitive to Perovskite thickness variations, which may translate to simpler manufacture and higher yield.

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