Bamboo Inspired Silicon Anodes with Ultrahigh Initial Coulombic Efficiency and High Capacity for the Li‐Ion Batteries

Abstract Silicon is regarded as the most promising candidate due to its ultrahigh theoretical energy density (4200 mAh g −1 ). However, the large volume expansion of silicon nanoparticles would result in the destruction of electrodes and a shortened cycle lifetime. Here, inspired by the natural structure of bamboo, the silicon anode with vascular bundle‐like structure is proposed to improve the electrochemical performance for the first time. The dense channel wall in the silicon anode can accommodate the volume change of silicon nanoparticles and the transport of ions and electrons is also enhanced. The obtained silicon anodes display excellent mechanical properties (50% compression resilience and the average peel force of 4.34 N) and good wettability. What more, the silicon anodes exhibit high initial coulombic efficiency (94.5%), excellent cycle stability (2100 mAh g −1 after 300 cycles) which stands out among the silicon anodes. Specially, the silicon anode with impressive areal capacity of 36.36 mAh cm −2 and initial coulombic efficiency of 84% is also achieved. This work offers a novel and efficient strategy for the preparation of the flexible electrodes with outstanding performance.