化学
光致发光
卤化物
发光
共沉淀
杂质
光电效应
钙钛矿(结构)
兴奋剂
金属
结晶学
无机化学
光电子学
材料科学
有机化学
作者
Chunli Zhao,Yuan Gao,Jianbei Qiu
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2023-10-10
卷期号:62 (42): 17382-17389
被引量:1
标识
DOI:10.1021/acs.inorgchem.3c02684
摘要
Two-dimensional (2D) layered double perovskites have attracted much attention because of their excellent photoelectric properties. However, few reports have been published on the synthesis of 2D layered double perovskites from halide perovskites as precursors. Here, we report that CsCdCl3 and Cs3Bi2Cl9 were synthesized by the coprecipitation method, and a two-dimensional layered double perovskite Cs4CdBi2Cl12 was readily synthesized by mixing the two halide perovskites. We doped different amounts of Mn2+ into CsCdCl3 to form CsCd1-xMnxCl3, which introduced impurity states into the energy level and exhibited an orange-red light emission that is characteristic of Mn2+. A series of 2D layered double perovskites Cs4Cd1-xMnxBi2Cl12 were synthesized from CsCd1-xMnxCl3 and Cs3Bi2Cl9, which showed a bright orange-yellow luminescence under ultraviolet excitation. The presence of high concentrations of Cd2+ in the two-dimensional layered double perovskites weakened the strong Mn-Mn coupling and suppressed the energy transfer to defects, thus minimizing nonradiative decay and promoting efficient energy transfer. Our work provides a new concept for the synthesis of low-dimensional metal halide perovskites with unique optical properties.
科研通智能强力驱动
Strongly Powered by AbleSci AI