材料科学
成核
降水
差示扫描量热法
合金
透射电子显微镜
亚稳态
扩散
相(物质)
微观结构
原位
化学工程
结晶学
冶金
热力学
纳米技术
化学
物理
有机化学
量子力学
气象学
工程类
作者
Robert Kahlenberg,Tomasz Wójcik,Georg Falkinger,Anna Lena Krejci,Benjamin Milkereit,Ernst Kozeschnik
出处
期刊:Acta Materialia
[Elsevier BV]
日期:2023-09-13
卷期号:261: 119345-119345
被引量:10
标识
DOI:10.1016/j.actamat.2023.119345
摘要
In the present work, we study the evolution of metastable and Cu-containing precursor precipitates into stable β-Mg2Si using in-situ transmission electron microscopy during continuous heating of an AA6061 aluminum alloy. The experiments indicate that the transformation into stable β-Mg2Si involves the release of Al and Cu atoms into the matrix phase combined with the rearrangement of Mg and Si at the interfaces. Nucleation of the β-Mg2Si precipitates predominantly occurs at the interface between the precursors and the aluminum matrix and at dispersoids. The term precipitate-related transformation is used to emphasize the reaction mechanism, where a new product precipitate nucleates next to a precursor and consumes it at its original location predominantly via interface diffusion. The in-situ investigations are complemented by an analysis of bulk samples and a comparison with differential scanning calorimetry measurements, which show excellent agreement.
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