The construction of S-scheme heterostructure in ultrathin WS2/Zn3In2S6 nanosheets for enhanced photocatalytic hydrogen evolution

Metal sulfide based photocatalysts are considered to be economic, environmentally benign and renewable. The rapid recombination of photogenerated electrons and holes and low solar energy utilization efficiency, however, remain a huge bottleneck. Herein, two-dimensional/two-dimensional (2D/2D) S-scheme WS2/Zn3In2S6 heterostructure with ultrathin nanosheets intervening between neighboring component has been designed. The large and intimate S-scheme heterojunctions facilitate interfacial charge separation/transfer and optimize the available redox potential. Besides, the ultrathin 2D/2D heterostructure ensures large specific surface area, maximized interface synergistic interaction, and effective exposure of surface active sites. As a result, 2 wt% WS2/Zn3In2S6 exhibits a high photocatalytic hydrogen production rate of 30.21 mmol·g−1·h−1 under simulated solar light illumination with an apparent quantum efficiency of 56.1% at 370 nm monochromatic light, far exceeding pristine Zn3In2S6 (6.65 mmol·g−1·h−1). Our work underscores the significance of integrating morphology engineering and S-scheme heterojunctions design for high-efficient and low-cost photocatalysts.