Microplastic-derived dissolved organic matter: Generation, characterization, and environmental behaviors

Microplastics (MPs) represent a substantial and emerging class of pollutants distributed widely in various environments, sparking growing concerns about their environmental impact. In environmental systems, dissolved organic matter (DOM) is crucial in shaping the physical, chemical, and biological processes of pollutants while significantly contributing to the global carbon budget. Recent findings have revealed that microplastic-derived dissolved organic matter (MP-DOM) constitutes approximately 10 % of the DOM present on the ocean surface, drawing considerable attention. Hence, this study's primary objective is to explore, the generation, characterization, and environmental behaviors of MP-DOM. The formation and characteristics of MP-DOM are profoundly influenced by leaching conditions and types of MPs. This review delves into the mechanisms of the generation of MP-DOM and provides an overview of a wide array of analytical techniques, including ultraviolet-visible (UV-Vis) spectroscopy, fluorescence spectroscopy, Fourier transform infrared spectroscopy (FTIR), and mass spectroscopy, used to assess the MP-DOM characteristics. Furthermore, this review investigates the environmental behaviors of MP-DOM, including its impacts on organisms, photochemical processes, the formation of disinfection by-products (DBPs), adsorption behavior, and its interaction with natural DOM. Finally, the review outlines research challenges, perspectives for future MP-DOM research, and the associated environmental implications.