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STUDY OF SORBSION PROPERTIES OF COPPER (II) ION WITH CHITOSAN BASED SORBENT

作者
S.M. Mammadova,A.R. Rajabli,Nargiz Tahmasib Rahimli,H.F. Aslanova,Ch.M. Seyidova,C.E. Guliyeva,Nizami Allahverdi Zeynalov,Dilgam Babir Tagiyev
出处
期刊:Azerbajčan himiâ žurnaly [Institute of Catalysis and Inorganic Chemistry]
卷期号: (2): 6-12 被引量:1
标识
DOI:10.32737/0005-2531-2023-2-6-12
摘要

Over the past few decades, a significant increase in the use of heavy metals has led to an increase in the amount of metals in the aquatic environment. For living organisms, among heavy metals, copper (II) is one of the toxic metals and one of the most common environmental pollutants. Excessive concentrations of Cu2+ ions can cause various diseases and intoxications in humans. In this regard, the use of absorbents for the sorption of metals is both an economically and technologically efficient method. Quaternized natural polymer chitosan was used as a sorbent to study the sorption properties of copper (II) ion. During the research, the optimal conditions of the sorption process was determined, pH effect of the environment, initial concentration of the metal on the sorption process were studied. The sorption capacity of the synthesized sorbent towards the Cu (II) ion was studied and it was determined that the maximum sorption capacity equal to 255 mg/g was at pH=4. Moreover the influence of copper (II) ion concentration on the sorption process was studied. It was found that the sorption capacity and sorption degree of the sorbent increase with an increase in the concentration of the Cu2+ ion in the solution. It was determined that the maximum sorption capacity was 406 mg /g, which corresponds to the concentration of copper (II) ion, equal to 10∙10-2 mol/L. The results show that quaternized chitosan-based sorbent can be successfully used for the sorption of Cu (II) ion

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