纳米棒
海水
尿素
纳米颗粒
纳米结构
电催化剂
分解水
材料科学
化学工程
电化学
纳米技术
催化作用
电极
化学
海洋学
光催化
有机化学
物理化学
工程类
生物化学
地质学
作者
Caihong Fang,Ran Li,Xin Wang,Fei Duan,Jiaping Lin,Yun Hu,Zhiqing Cui
标识
DOI:10.1016/j.cej.2024.149498
摘要
The heterogeneous nanoparticles−nanorod Ni−NiMoO4 nanostructures grown in situ on nickel foam (Ni−NiMoO4/NF) were rationally engineered as efficient electrocatalysts. The morphological and compositional features cooperatively propel high-performance electrocatalysis to hydrogen evolution reaction (η10, η100, and η200 values are 26/84/113 mV in fresh water and 27/101/132 mV in seawater), urea oxidation reaction (η10, η100, and η200 values are 1.321/1.340/1.356 and 1.329/1.344/1.361 V in fresh/seawater). The Ni−NiMoO4/NF nanostructures therefore perform a low cell voltage of 1.506/1.509@10 mA cm−2 in fresh/sea water. Specifically, the record cell voltage even drops to as low as 1.339/1.361 V in fresh/sea water for overall urea splitting (OUS) reaction with a long-term stability for 240 h@100 mA cm−2 toward OUS in seawater. More importantly, to realize a green manner, we also evaluated a solar-driven H2 production. Even in seawater, H2 gas was collected in high speed under solar illumination on a commercial solar panel.
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