Inorganic metal oxide‐reinforced polymer‐based flexible inorganic nanocomposite for UV shielding applications

纳米复合材料 材料科学 金属 氧化物 电磁屏蔽 聚合物 复合材料 无机聚合物 聚合物纳米复合材料 高分子化学 化学工程 冶金 工程类
作者
Mahadeva Prasad Puttaswamy,Nithin Kundachira Subramani,Sachhidananda Shivanna,Nanjundaswamy Gumatapura Siddamallappa,Madhukar Beejaganahalli Sangameshwara,Radu Urs
出处
期刊:Journal of Applied Polymer Science [Wiley]
卷期号:141 (33) 被引量:10
标识
DOI:10.1002/app.55837
摘要

Abstract This investigation reveals the successful incorporation of strontium‐doped thorium oxide (SrThO 3 ) NPs into polyvinyl alcohol (PVA) polymer nanocomposites. The fabrication process of these PVA nanocomposites entails utilizing varying amounts (0.5, 1.0, 2.0, and 4.0 wt%) of SrThO 3 nanofillers through a straightforward solution casting technique. The microstructure and overall structure of the resulting polymer nanocomposites were analyzed using powdered x‐ray diffraction for crystalline structure and Fourier transform infrared (FTIR) spectroscopy for molecular composition. The introduced SrThO 3 nanofiller demonstrates a strong affinity for the hydroxyl groups present in the PVA polymer, a phenomenon validated through FTIR spectroscopy. In order to comprehend the impact of doping, the surface morphology of the PVA polymer nanocomposites underwent examination via scanning electron microscopy. The absorption and transmission of light were quantitatively assessed using UV–visible spectroscopy. The excitation and emission behaviors of electrons in both the PVA and SrThO 3 ‐doped PVA nanocomposites were scrutinized through photoluminescence spectroscopy. Furthermore, the extent of UV light absorption was investigated by studying the degradation of methylene blue dye, a substance known for its sensitivity to UV light. Results indicate that the intentional incorporation of SrThO 3 NPs significantly enhances UV stability.
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