Homogenic Boundary Effect Boosted Oxygen Evolution Reaction in α/β‐NiMoO4 for Rechargeable Aqueous Zn‐Air Battery

Abstract Rechargeable Zn‐air batteries (ZAB) represent a promising avenue for sustainable energy storage, boasting high energy density, cost‐effectiveness, scalability, and environmental friendliness. However, the sluggish redox kinetics and limited cycle life of bifunctional oxygen evolution/reduction (OER/ORR) electrocatalysts impede the further practical development of ZABs. In this study, homogenic boundary effect within α/β‐NiMoO 4 is introduced as a superior electrocatalyst for ZAB. Through in situ poikilothermic X‐ray diffraction, X‐ray absorption spectroscopy, and theoretical investigations, the active Ni atoms exhibit more effective electron transfer at α/β‐NiMoO 4 due to the homogenic boundary effect is unveiled. Furthermore, the presence of oxygen vacancies and lattice distortions at these boundaries significantly reduces the thermodynamic barrier of OER to a mere 0.46 V. Consequently, α/β‐NiMoO 4 demonstrates a remarkably low overpotential of 270 mV at 10 mA cm −2 for the bottlenecked OER, along with prolonged durability (150 h) and a high specific capacity (745 mAh g −1 at 5 mA cm −2 ) for ZAB. This study underscores the efficacy of homogenic boundary effects in enhancing electrocatalytic activities, offering great promise for the advancement of sustainable energy systems.