催化作用
贵金属
化学
5-羟甲基糠醛
羟甲基
生物量(生态学)
催化氧化
有机化学
组合化学
海洋学
地质学
作者
Deyang Zhao,Ting Su,Yantao Wang,Rajender S. Varma,Christophe Len
标识
DOI:10.1016/j.mcat.2020.111133
摘要
5-Hydroxymethylfurfural (HMF) has been considered as one of the most promising versatile biomass based platform molecules. This review discusses recent advances in catalytic oxidation of HMF towards 2, 5-furandicarboxylic acid (FDCA) as well as other HMF oxidation intermediates: 2,5-diformylfuran (DFF), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA) deploying noble, non-noble, metal-free and biocatalytic systems in conventional batch protocols; reaction mechanisms and the reaction conditions are well deliberated. Selective HMF downstream oxidation products are obtained via catalyst modifications such as the nature of metal, preparative method as well the property of deployed support. HMF oxidation, an important and integral biomass-based valorization process towards valuable chemicals, deserves more attention.
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