成核
钻石
外延
降水
溶解
基质(水族馆)
Crystal(编程语言)
碳纤维
表面能
薄脆饼
X射线光电子能谱
材料科学
结晶学
化学物理
晶体生长
化学
化学工程
纳米技术
物理化学
冶金
物理
地质学
复合材料
图层(电子)
有机化学
海洋学
复合数
程序设计语言
气象学
计算机科学
工程类
作者
Yang Wang,Weihua Wang,Guoyang Shu,Shishu Fang,Bing Dai,Jiaqi Zhu
标识
DOI:10.1016/j.jcrysgro.2021.126047
摘要
The heteroepitaxial growth of single crystal diamond requires substrate of high quality, and Ir(1 0 0) is an ideal substrate which can meet the standard perfectly. However, the reason of its outstanding performance still remains unclear. In this paper, the interaction mechanism between carbon atoms and Ir (1 0 0) surface at the initial stage of nucleation and its uniqueness caused by distinctive energy changes compared with (1 0 0) faces of Cu and Ni are explained by first-principle calculation, which acts as a dominating factor in the transformation from epitaxial films to single crystal wafers. The energy driving force of the dissolution-precipitation process is described, which can completely accord with bias-enhanced nucleation(BEN) method to illustrate the effect of voltage on diamond nucleation. The precipitation of carbon atoms and appearance of primary nuclei with the increase of carbon concentration are discussed, which can effectively explain the special phenomenon of the “domain” formation. A carbon-rich pre-treatment before primary nucleation on Ir (1 0 0) surface shows that the initial nucleation process can form supersaturated solid solution of carbon in Ir (1 0 0), which can greatly accelerate the subsequent dissolution-precipitation circulation.
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