兴奋剂
吸附
选择性
丙酮
X射线光电子能谱
材料科学
纳米颗粒
分子
氧气
无机化学
金属
分析化学(期刊)
光电子学
纳米技术
化学工程
化学
催化作用
冶金
有机化学
工程类
作者
Roh Eul Yoo,Andreas T. Güntner,Yunji Park,Hyun Jun Rim,Hyun Sook Lee,Wooyoung Lee
标识
DOI:10.1016/j.snb.2018.12.001
摘要
The development of chemoresistive gas sensors for environmental and industrial air monitoring as well as medical breath analysis is investigated. Flame-made ZnO nanoparticles (NPs) doped with 1 at% Aluminum exhibited higher sensing performance (response 245, response time ∼ 3 s, and sensitivity 23 ppm−1) than pure ZnO and those made by a hydrothermal method (HT) (56, ∼ 12 s, and 4 ppm−1) for detection of 10 ppm acetone. Furthermore, their sensing response of ∼10 to 0.1 ppm of acetone at 90% RH is superior to other metal oxide sensors and they feature good acetone selectivity to other compounds (including NH3, isoprene and CO). Characterization by N2 adsorption, X-ray photoelectron and UV–vis spectroscopies reveals that the improved sensing performance of flame-made Al-doped ZnO NPs is associated primarily to a higher density of oxygen vacancies than pure ZnO and all HT-made NPs. This leads to a greater number of adsorbed oxygen ions on the surfaces of Al-doped ZnO NPs, which can react with acetone molecules.
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