催化作用
电解水
纳米技术
化学
生化工程
电催化剂
制氢
析氧
电解
合理设计
电化学
计算机科学
分解水
范围(计算机科学)
桥接(联网)
溶解
材料科学
质子交换膜燃料电池
可扩展性
氢经济
铱
环境科学
燃料电池
作者
Robel Mehari Tesfaye,Ayon Karmakar,Joy Marie Mora,Mrittunjoy Sarker,Po-Ya Abel Chuang
标识
DOI:10.1021/acsaem.5c03459
摘要
Ruthenium-based electrocatalysts have emerged as a promising alternative to iridium when it comes to the oxygen evolution reaction (OER), particularly in proton exchange membrane water electrolyzers (PEMWE). Although Ru-based catalysts exhibit superior intrinsic activity, their widespread adoption is hindered by stability challenges under acidic operating conditions, necessitating strategies to mitigate dissolution and degradation. This review offers an in-depth examination of Ru-based catalysts, highlighting the critical role of support materials in determining their catalytic activity, electronic conductivity, and long-term stability. The discussion is systematically organized according to the type of support material, each offering distinct advantages and limitations. Reported experimental studies are compiled and critically analyzed to highlight representative advances in synthesis strategies and corresponding electrochemical performance, with emphasis on catalytic activity and durability. By consolidating recent progress and performance benchmarks, this review provides a coherent overview of the current landscape of Ru-based OER electrocatalysts. Finally, future research directions are proposed to accelerate the development of robust, high-performance Ru-based catalysts capable of replacing iridium in large-scale PEM water electrolysis applications. By bridging insights across materials design, synthesis, and electrochemical evaluation, this review aims to guide the rational development of next-generation Ru-based electrocatalysts that combine high activity, stability, and scalability for sustainable hydrogen production.
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