Effect of Ni Interlayer on Microstructure and Properties of C276 Hastelloy/Q235 Steel Cladding Plates

材料科学 包层(金属加工) 腐蚀 微观结构 碳化物 冶金 复合材料 合金 压痕硬度 各向同性腐蚀 弯曲分子几何 晶间腐蚀 降水 氧化物 X射线光电子能谱 剪切(地质)
作者
Lin Lv,Mingfang Wu,Fei Long,Mingkuan Zhou,Juan Pu
出处
期刊:Coatings [Multidisciplinary Digital Publishing Institute]
卷期号:16 (4): 425-425
标识
DOI:10.3390/coatings16040425
摘要

C276 Hastelloy/Q235 Steel cladding plates were prepared by vacuum-sealed hot rolling (VSHR) with a small hole. The effects of different Ni interlayers on the macro-morphology, microstructure, mechanical properties and corrosion resistance of the cladding plates were systematically investigated. The results indicated that without an interlayer, a large number of Mo-rich white M6C particles formed near the C276 Hastelloy side, along with the formation of black Cr-Mn oxides at the interface. The addition of the Ni interlayer suppressed the diffusion of the C element from the Q235 Steel toward the C276 Hastelloy, consequently reducing the precipitation of M6C carbides and Cr-Mn oxides. When the Ni interlayer thickness was 0.5 mm, the M6C carbides on the Hastelloy side disappeared completely. The incorporation of a Ni interlayer increased the hardness of the C276 Hastelloy side and the interface layer, as well as the shear strength of the cladding plate. This was mainly because the Ni interlayer acted as a barrier to suppress the development of a Mo/Cr-depleted zone adjacent to the C276 Hastelloy and decrease interfacial Cr-Mn oxides, thus enhancing interfacial bonding. Under all three conditions, the cladding plates were bent without cracking. Moreover, the addition of a Ni interlayer also improved the corrosion resistance of the cross-section of the C276 Hastelloy. XPS analysis of the passive film revealed that the corrosion resistance was primarily attributed to the formation of Mo- and Cr-containing oxides on the surface. The corrosion resistance reached the optimal with the Ni interlayer thickness of 0.5 mm, in which Mo and Cr played a crucial role.

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