编织
铜
共价有机骨架
亚胺
材料科学
醛
共价键
结晶学
化学
高分子化学
复合材料
冶金
有机化学
催化作用
作者
Yuzhong Liu,Yanhang Ma,Yingbo Zhao,Xixi Sun,Felipe Gándara,Hiroyasu Furukawa,Zheng Liu,Hanyu Zhu,Chenhui Zhu,Kazu Suenaga,Peter Oleynikov,Ahmad S. Alshammari,Xiang Zhang,Osamu Terasaki,Omar M. Yaghi
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2016-01-21
卷期号:351 (6271): 365-369
被引量:571
标识
DOI:10.1126/science.aad4011
摘要
Weaving organic threads Woven fabrics are inherently flexible. Liu et al. created a molecular fabric analog using metal-organic frameworks (see the Perspective by Gutierrez-Puebla). Phenanthroline ligands on a copper metal complex directed the addition of organic linkers via imine bonds to create helical organic threads with woven texture. Removing the copper allowed the strands to slide against each other and increased the elasticity of the material 10-fold. Science , this issue p. 365 ; see also p. 336
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