钒
键裂
催化作用
劈理(地质)
化学
选择性
木质素
芳基
药物化学
有机化学
组合化学
材料科学
断裂(地质)
复合材料
烷基
作者
Susan K. Hanson,Ruilian Wu,Louis A. Silks
标识
DOI:10.1002/anie.201107020
摘要
The aerobic oxidation of a phenolic lignin model compound with a vanadium catalyst results in the oxidative cleavage of the CC bond between the aryl ring and the adjacent hydroxy-substituted carbon atom (see scheme). Labeling experiments indicate key mechanistic differences to a previously reported related CO bond cleavage reaction. The selectivity in CC versus CO bond cleavage depends on the choice of the vanadium catalyst. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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