Al2O3 films were grown on Si substrates by microwave generated remote plasma assisted atomic layer deposition technique (PA-ALD). The thickness of the Al2O3 films would be controlled by the ALD cycles. For the X-ray photoelectron spectroscopy results of Al2O3 film, carbon compounds didn't exist into Al2O3 film. The MOS capacitor obtained by PA-ALD had small hysteresis and the interface trap density of 4.5x1010cm-2eV-1.