光电流
光电导性
光强度
材料科学
聚合物太阳能电池
异质结
退火(玻璃)
电子迁移率
短路
电流密度
光电子学
空间电荷
有机太阳能电池
富勒烯
凝聚态物理
聚合物
太阳能电池
电子
分子物理学
化学
物理
电压
光学
复合材料
量子力学
作者
L. Jan Anton Koster,V.D. Mihailetchi,Huaqing Xie,Paul W. M. Blom
摘要
A typical feature of polymer/fullerene based solar cells is that the current density under short-circuit conditions (Jsc) does not scale exactly linearly with light intensity (I). Instead, a power law relationship is found given by Jsc∝Iα, where α ranges from 0.85 to 1. In a number of reports this deviation from unity is speculated to arise from the occurrence of bimolecular recombination. We demonstrate that the dependence of the photocurrent in bulk heterojunction solar cells is governed by the build-up of space-charge in the device as a consequence of a difference in electron- and hole mobility. We have verified this for an experimental model system in which the mobility difference can be tuned from one to three orders of magnitude by changing the annealing treatment.
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