Simultaneous adsorption for cationic and anionic dyes using chitosan/electrospun sodium alginate nanofiber composite sponges

The coexistence of anionic and cationic dyes in dye wastewater has highlighted a great necessity to develop amphoteric adsorbents for their simultaneous removal. Herein, an amphoteric composite sponge was successfully fabricated by combining chitosan with electrospun sodium alginate nanofiber using lyophilization in acetic acid/water/dioxane mixed solvents, which owned the abundant functional groups and superior microstructure of interconnected pores and nanoscale fibers, beneficial for the adsorption capacity improvement. The optimum adsorption capacities for Acid Blue-113 and Rhodamine B were 926.2 ± 25.7 mg/g and 695.4 ± 17.0 mg/g, respectively, much higher than that of the controlled sample prepared with chitosan and non-spinning sodium alginate in traditional acetic acid/water solvents. Meanwhile, the sponge provided with the superior adsorption performance under various pH environment and cyclic adsorption. Importantly, it had considerable simultaneous adsorption capacity for binary system containing anionic and cationic dyes. Overall, the chitosan/electrospun sodium alginate nanofiber composite sponge shows potential for complex wastewater treatment.