化学
金属有机骨架
产量(工程)
选择性
热液循环
纳米技术
溶剂
铝
化学工程
有机化学
相(物质)
催化作用
有机合成
冶金
材料科学
吸附
工程类
作者
Jiahong Li,Matthew J. Hurlock,Vitaliy Goncharov,Xiaoyü Li,Xiaofeng Guo,Qiang Zhang
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2021-03-12
卷期号:60 (7): 4623-4632
被引量:15
标识
DOI:10.1021/acs.inorgchem.0c03598
摘要
Aluminum-based metal–organic frameworks (Al-MOFs) have shown promise as commercially valuable materials due to the variety of applications, excellent thermal, hydrothermal, and chemical stabilities, and the abundance of aluminum. In this work, for the first time, we report the solvent-free synthesis of the aluminum trimesate (Al-BTC) MOFs (MIL-100(Al), MIL-96(Al), and MIL-110(Al)) with phase selectivity and high yield. These MOFs were traditionally prepared with HF, HNO3, and bulk solvents, but these methods struggled to produce pure-phase isolations. The solvent-free strategy provides valuable insight into the future industrial scale-up production of the Al-MOFs and promotes the potential commercialization of such materials.
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